Saturday, October 17, 2009

Hot Ice?


OK, this is something cool I did a while ago. "Hot Ice" is is sodium acetate, you get it as a white mush from the volcano baking soda and vinegar reaction along with carbon dioxide (maybe I'll do that sometime), that is supercooled. Supercooling is where you take a liquid and cool it down to lower its normal freezing point without its phase changing (the state of matter it's in, solid, liquid, gas, and plasma). You do this by making the liquid totally pure. When a liquid turns into a solid, it becomes a crystal. There is the exception of amorphous solids like glass, that are physically solids, but have no order between the atoms and do flow, they are just very viscous, so it takes hundreds of years. For a crystal to form, it needs an object to grow off of. 
When water is completely pure, it has no dust in it to start growing crystals. Water normally it freezes at 0 °C (32 °F), but when it's pure, it freezes at -42 °C (-43.6 °F). It's able to do this because the water molecules start clumping together so tightly that they form an unstable crystal that melts at a temperature higher than -42° C. That allows the water to form crystals. 
Sodium acetate does the same thing. Since it is not a liquid at room temperature, it has to be dissolved in a liquid. You have to have a lot of sodium acetate in the solution, so you have to supersaturate it by heating up the liquid and dissolving the sodium acetate so more of it is in the liquid than you normally could dissolve. It's like rock candy, you dissolve as much sugar as you can in boiling water, supersaturating it, and then place a starter crystal and after about a week, it forms a giant sugar crystal. So after supersaturating the sodium acetate at around 58 °C (136.4 °F), and then heating it up to 100 °C (212 °F), you cool it down to room temperature. There you have it, all you have to do it touch it and it will crystalize and heat up in an exothermic reaction (it does this because of electron spacing allows atoms not to hold as much energy, so they release it as heat. I'll explain it in another experiment). 
You can get powdered sodium acetate online to do this but you can also just go buy some hand warmers (I got a couple at REI). They're plastic bags filled with a clear liquid (sodium acetate) with a metal coin that you flex to start the reaction. I tried to make some, concentrating the white mush from the baking soda and vinegar experiment. The proportions weren't correct so there was left over vinegar and baking soda so that most of it decomposed when I concentrated making it brown and the rest of the impurities made it crystallize. Well, I hope you thought this was cool, I have a video posted of one of the hand warmers, and if I ever make my own sodium acetate I'll post that too. Oh, also here's a recipe for making the sodium acetate with baking soda and vinegar.

Sorry!

I haven't been able to update this every week and I'm not going to try. I have too much going on, and I don't have time to even think of cool experiments that I could tape. If you have any ideas, post them in the comments.

Sunday, September 13, 2009

Dancing Corn Starch!?!?!









Hey, yesterday I did a totally awesome experiment with dancing corn starch. I suggest doing this in the basement or out side where it's okay to get messy and there's an outlet. You'll need a junky old speaker to use and you'll have to hook it up to an amplifier with a computer to generated the sound. I use a Mac so I got a free app called Tone Gen from the apple website so for those who have PC's you'll have to look around or hook up a keyboard. You'll need the corn starch (you can find it at super markets) to be at the consistency that you can punch it with your fist and it will be solid. For those who don't know what corn starch is, it's a powder used as a thickener in gravies instead of flower and if you mix in with water it has the cool property of being "Non-Newtonian", meaning when you squeeze it, it's a solid and when you let go it's a liquid. So, when you mix up the corn starch I suggest putting it on a Styrofoam plate if your speaker cone is cloth, and putting the plate on a plastic bag so you don't end breaking the speaker. Then if you have the app set it to a single tone ( I suggest 28 Hz if your speaker can go that low, though it works to about 35 Hz). If you only have a keyboard you'll need to go as low as you can and if you have a tuba setting you should do that and crank up the volume as high as it can go without the amplifier burning a fuse or the speaker popping. once you have this set up, hopefully it will start wiggling in the middle and you can get it to move around a pit by poking it with a pencil (or using your hands ;-). If you have the computer set up you can play really loud music in the background :-) So, you know, the louder the volume the more it moves around.  
             So what I think is happing is that with all liquids low sound makes them vibrate and make cool patterns. With corn starch it has more of a structure with all the vibrations, becoming semisolid making the patterns be able to "climb". while this stuff is out a fun thing to do is to do a hearing test. Start at 1 Hz and go up on single tone with the plus and minus buttons in the top left corner, seeing how high and low you can hear.
         note: be careful when going to high Hz and let the tester change the volume so you don't end up shattering their ear drums. Also, don't listen to the high notes for more than a minute or two because it might cause ear damage.

Saturday, September 12, 2009

Hey, hopefully every one or two weeks I'm going show a cool science experiment and video along with it. I'll keep this going for a while and putting things in as I do them, trying to keep them simple enough to do at home.